Hmm....if it's 15 years old, you might just get a new wheel anyway....chances are the hub races are pretty worn, too. There's nothing wrong with rebuilding good parts, though. You might find that you can order a single wheel from a shop for about the same as what it'll cost you to get the materials you need (if the hub is bad). Also, if it's a rim-brake wheel, check the sidewalls carefully. If they've worn badly, you can blow out a wheel at some point (seen it happen, and it isn't pretty!).
The Park Tools websites covers truing a little bit, but it's not great. I'd recommend you get the book The Bicycle Wheel from Jobst Brandt if you really want to learn.....it's not a fun read, but it has the best instructions, I think. There's another wheel-building book that's spiral-bound, can't remember the name of it.....it's a good one, too. The Bicycling Magazine books for road and mtn bike maintenance/repair have an ok section on truing, and it's easier to follow for a beginner (so does the Zinn book for repairs). You can probably get 2 or 3 of those at Barnes and Noble, possibly even the library for the repair books.
Spoke breakage can happen from age and wear (and rust), but usually it's from a wheel that either isn't built properly or isn't made for the use it's getting. Sounds like maybe yours are just old and used, or maybe it has cheap spokes. Kinda important to try to figure out what's going on before you waste too much time or money in it.